{"id":9169,"date":"2022-06-13T11:22:46","date_gmt":"2022-06-13T09:22:46","guid":{"rendered":"https:\/\/www.alsys-group.com\/?p=9169"},"modified":"2025-11-03T15:04:05","modified_gmt":"2025-11-03T14:04:05","slug":"spent-caustic-recycle","status":"publish","type":"post","link":"https:\/\/www.alsys-group.com\/en\/membrane-en\/spent-caustic-recycle\/","title":{"rendered":"Spent caustic recycle"},"content":{"rendered":"<h2>Spent caustic recycle<\/h2>\n<p><a href=\"https:\/\/www.alsys-group.com\/en\/group\/location\/alsys-usa-ceramem\/\">CeraMem<\/a> proposes to spent caustic recycle and surfactants using tangential filtration CeraMem\u00ae ceramic membranes.<\/p>\n<p style=\"text-align: center;\"><a href=\"https:\/\/www.alsys-group.com\/app\/uploads\/2021\/11\/membrane-housing.jpg\"><img decoding=\"async\" loading=\"lazy\" class=\"aligncenter wp-image-7963 size-full\" src=\"https:\/\/www.alsys-group.com\/app\/uploads\/2021\/11\/membrane-housing.jpg\" alt=\"CeraMem\u00ae ceramic membrane in housing\" width=\"907\" height=\"189\" srcset=\"https:\/\/www.alsys-group.com\/app\/uploads\/2021\/11\/membrane-housing.jpg 907w, https:\/\/www.alsys-group.com\/app\/uploads\/2021\/11\/membrane-housing-300x63.jpg 300w, https:\/\/www.alsys-group.com\/app\/uploads\/2021\/11\/membrane-housing-768x160.jpg 768w\" sizes=\"(max-width: 907px) 100vw, 907px\" \/><\/a>CeraMem\u00ae Ceramic Membrane in housing<\/p>\n<h3>\u00a0<\/h3>\n<h2>The Client<\/h2>\n<p>PRO-TEC Coating Company was established as a joint partnership in 1990 and is strategically located in Northwestern Ohio.<\/p>\n<p>Their 730,000-square-foot plant, located near Leipsic, Ohio, produces high quality coated steel products with output of over 1.1 million tons annually.<\/p>\n<p>PRO-TEC is recognized as a leader in Advanced High Strength Steels (AHSS) in the United States.<\/p>\n<p>&nbsp;<\/p>\n<h2>Project Background<\/h2>\n<p>PRO-TEC\u2019s plant in Leipsic is one of the largest facilities in North America producing hot-dipped galvanized\/galvannealed steel products. The process of galvanizing\/galvannealing begins with high-quality, cold rolled steel coils.<\/p>\n<p style=\"text-align: center;\"><a href=\"https:\/\/www.alsys-group.com\/app\/uploads\/2022\/06\/2022-011-photo1bis-30x10-1.png\"><img decoding=\"async\" loading=\"lazy\" class=\"aligncenter wp-image-9441 size-full\" src=\"https:\/\/www.alsys-group.com\/app\/uploads\/2022\/06\/2022-011-photo1bis-30x10-1.png\" alt=\"PRO-TEC Coating Company\u2019s plant in Leipsic - spent caustic recycle\" width=\"1134\" height=\"302\" srcset=\"https:\/\/www.alsys-group.com\/app\/uploads\/2022\/06\/2022-011-photo1bis-30x10-1.png 1134w, https:\/\/www.alsys-group.com\/app\/uploads\/2022\/06\/2022-011-photo1bis-30x10-1-300x80.png 300w, https:\/\/www.alsys-group.com\/app\/uploads\/2022\/06\/2022-011-photo1bis-30x10-1-1024x273.png 1024w, https:\/\/www.alsys-group.com\/app\/uploads\/2022\/06\/2022-011-photo1bis-30x10-1-768x205.png 768w\" sizes=\"(max-width: 1134px) 100vw, 1134px\" \/><\/a>PRO-TEC Coating Company\u2019s plant in Leipsic<\/p>\n<p>&nbsp;<\/p>\n<h2>Rolled Steel Preparation<\/h2>\n<h3>Management of Spent Caustic recycle<\/h3>\n<p>Prior to surface treatment, the raw steel is cleaned with a caustic degreaser. This process results in substantial quantities of spent caustic cleaner that contains oils and greases, grit, water, and other solids. The spent cleaner is collected and sent to disposal offsite.<\/p>\n<p>The disposal of the spent cleaner represents a significant expense in not only disposal, but also in the costs of replacing the caustic degreaser for production.<\/p>\n<p>Despite several attempts to solve this issue, a cost-effective and technically feasible solution could not be achieved. PRO-TEC contacted CeraMem to explore alternative technologies and processes. The solution required that both certain cost and performance objectives be met.<\/p>\n<p>&nbsp;<\/p>\n<h2>Performance Testing<\/h2>\n<h3>Chemical Recovery and Waste Reduction<\/h3>\n<p>CeraMem proposed a system comprised of CeraMem\u00ae ceramic membranes. CeraMem membranes are ideal for this application due to the ability to tolerate high operating temperatures, aggressive cleaning regimens, and resistance to high pH levels. After some initial laboratory testing, a full-size, crossflow membrane system was designed and built in 2009. The goal of the system was to recover the spent caustic degreaser to a specified rate and quality, in order to vastly reduce the amount of waste generated.<\/p>\n<p><strong>Download CeraMem\u00ae technical datasheet (PDF): <a href=\"https:\/\/www.alsys-group.com\/app\/uploads\/2021\/03\/alsys-us0602-ceramem-ceramic-membranes-and-modules-data-sheet-v11.25.pdf\">ALSYS &#8211; US0602 &#8211; CERAMEM CERAMIC MEMBRANES AND MODULES &#8211; Data Sheet &#8211; V11.25<\/a><\/strong><\/p>\n<p style=\"text-align: center;\"><a href=\"https:\/\/www.alsys-group.com\/app\/uploads\/2022\/06\/2022-011-photo3-30x10-1.png\"><img decoding=\"async\" loading=\"lazy\" class=\"aligncenter wp-image-9433 size-full\" src=\"https:\/\/www.alsys-group.com\/app\/uploads\/2022\/06\/2022-011-photo3-30x10-1.png\" alt=\"CeraMem\u00ae ceramic membrane system to spent caustic recycle\" width=\"1134\" height=\"378\" srcset=\"https:\/\/www.alsys-group.com\/app\/uploads\/2022\/06\/2022-011-photo3-30x10-1.png 1134w, https:\/\/www.alsys-group.com\/app\/uploads\/2022\/06\/2022-011-photo3-30x10-1-300x100.png 300w, https:\/\/www.alsys-group.com\/app\/uploads\/2022\/06\/2022-011-photo3-30x10-1-1024x341.png 1024w, https:\/\/www.alsys-group.com\/app\/uploads\/2022\/06\/2022-011-photo3-30x10-1-768x256.png 768w\" sizes=\"(max-width: 1134px) 100vw, 1134px\" \/><\/a>CeraMem\u00ae Ceramic Membrane System<\/p>\n<p>&nbsp;<\/p>\n<h3>The design criteria of the caustic recovery system\u00a0 were the following:<\/h3>\n<ul>\n<li>UF (Ultrafiltration) membrane\u00a0: Titanium oxide, 0.01\u03bcm pore size<\/li>\n<li>Recovery: 95%<\/li>\n<li>UF feed composition&nbsp;: 4% TSS, 1% oil &amp; grease<\/li>\n<li>Permeate composition:&nbsp;: TSS and Oil &amp; Grease &lt;10 mg\/l, Turbidity &lt;5 NTU<\/li>\n<li>Operating temperature: &gt; 50\u02daC; pH 10-13<\/li>\n<\/ul>\n<p>&nbsp;<\/p>\n<h3>System highlights<\/h3>\n<ul>\n<li>&gt;95% Caustic cleaner recovery resulting in 95% reduction in chemical make-up costs<\/li>\n<li>Reduced environmental impact<\/li>\n<li>&gt;20x less waste sludge and associated disposal costs<\/li>\n<li>Short payback period<\/li>\n<li>The system is fully automated. And the system was pre-engineered and required minimal installation and commissioning<\/li>\n<li>The system achieved 95% recovery and the permeate quality met the design criteria for TSS and dispersed oil &amp; grease.<\/li>\n<\/ul>\n<p>&nbsp;<\/p>\n<h2>Spent Caustic Recycle Results<\/h2>\n<p>Satisfied that the system met the design requirements during commissioning, the system was fully integrated into PRO-TEC\u2019s caustic degreaser blow down treatment operation, and has been operated by PRO-TEC since 2010.<\/p>\n<p>To date, the CeraMem system at PRO-TEC has exceeded performance requirements while achieving a large reduction in the degreaser waste and makeup (&gt;95%) for the facility. Recycling the caustic and the surfactants has minimized the impact to the environment.<\/p>\n<p style=\"text-align: center;\"><a href=\"https:\/\/www.alsys-group.com\/app\/uploads\/2022\/06\/2022-011-photo2-en-30x10-1.png\"><img decoding=\"async\" loading=\"lazy\" class=\"aligncenter wp-image-9445 size-full\" src=\"https:\/\/www.alsys-group.com\/app\/uploads\/2022\/06\/2022-011-photo2-en-30x10-1.png\" alt=\"Spent Caustic Recycle - Process Overview\" width=\"1134\" height=\"378\" srcset=\"https:\/\/www.alsys-group.com\/app\/uploads\/2022\/06\/2022-011-photo2-en-30x10-1.png 1134w, https:\/\/www.alsys-group.com\/app\/uploads\/2022\/06\/2022-011-photo2-en-30x10-1-300x100.png 300w, https:\/\/www.alsys-group.com\/app\/uploads\/2022\/06\/2022-011-photo2-en-30x10-1-1024x341.png 1024w, https:\/\/www.alsys-group.com\/app\/uploads\/2022\/06\/2022-011-photo2-en-30x10-1-768x256.png 768w\" sizes=\"(max-width: 1134px) 100vw, 1134px\" \/><\/a><i>Spent<\/i> <i>Caustic<\/i> <i>Recycle<\/i> <i>&#8211;<\/i> <i>Process<\/i> <i>Overview<\/i><\/p>\n","protected":false},"excerpt":{"rendered":"<p>Spent caustic recycle CeraMem proposes to spent caustic recycle and surfactants using tangential filtration CeraMem\u00ae ceramic membranes. CeraMem\u00ae Ceramic Membrane in housing \u00a0 The Client PRO-TEC Coating Company was established as a joint partnership in 1990 and is strategically located in Northwestern Ohio. Their 730,000-square-foot plant, located near Leipsic, Ohio, produces high quality coated steel [&hellip;]<\/p>\n","protected":false},"author":4,"featured_media":9437,"comment_status":"closed","ping_status":"open","sticky":false,"template":"","format":"standard","meta":[],"categories":[54],"tags":[],"acf":[],"taxonomies":{"categories":[{"term_id":54,"name":"Membrane","slug":"membrane-en","term_group":0,"term_taxonomy_id":54,"taxonomy":"category","description":"","parent":0,"count":61,"filter":"raw","term_order":"0","cat_ID":54,"category_count":61,"category_description":"","cat_name":"Membrane","category_nicename":"membrane-en","category_parent":0}]},"_links":{"self":[{"href":"https:\/\/www.alsys-group.com\/en\/wp-json\/wp\/v2\/posts\/9169"}],"collection":[{"href":"https:\/\/www.alsys-group.com\/en\/wp-json\/wp\/v2\/posts"}],"about":[{"href":"https:\/\/www.alsys-group.com\/en\/wp-json\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"https:\/\/www.alsys-group.com\/en\/wp-json\/wp\/v2\/users\/4"}],"replies":[{"embeddable":true,"href":"https:\/\/www.alsys-group.com\/en\/wp-json\/wp\/v2\/comments?post=9169"}],"version-history":[{"count":13,"href":"https:\/\/www.alsys-group.com\/en\/wp-json\/wp\/v2\/posts\/9169\/revisions"}],"predecessor-version":[{"id":11382,"href":"https:\/\/www.alsys-group.com\/en\/wp-json\/wp\/v2\/posts\/9169\/revisions\/11382"}],"wp:featuredmedia":[{"embeddable":true,"href":"https:\/\/www.alsys-group.com\/en\/wp-json\/wp\/v2\/media\/9437"}],"wp:attachment":[{"href":"https:\/\/www.alsys-group.com\/en\/wp-json\/wp\/v2\/media?parent=9169"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"https:\/\/www.alsys-group.com\/en\/wp-json\/wp\/v2\/categories?post=9169"},{"taxonomy":"post_tag","embeddable":true,"href":"https:\/\/www.alsys-group.com\/en\/wp-json\/wp\/v2\/tags?post=9169"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}